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Citation Analysis of Tamio Hayashi's Publications

 

Database:

SciFinder (for the reports published in 1995-present)

Web of Science (for those published in other years)

Last Update:

December 09, 2011

 

Number of original papers: 375

Number of review articles and books: 107

Total number of citations: 24,899

H-Index: 85

 

Rank

Counts

Publication

(Paper No.)

1

653

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): An Effective Catalyst for Cross-Coupling of Secondary and Primary Alkyl Grignard and Alkylzinc Reagents with Organic Halides.

Hayashi, T.; Konishi, M.; Kobori, Y.; Kumada, M.; Higuchi, T.; Hirotsu, K.

J. Am. Chem. Soc. 1984, 106, 158-163

(054)

2

607

Rhodium-Catalyzed Asymmetric 1,4-Addition and Its Related Asymmetric Reactions.

Hayashi, T.; Yamasaki, K.

Chem. Rev. 2003, 103, 2829-2844

(R082)

3

475

Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex.

Ito, Y.; Sawamura, M.; Hayashi, T.

J. Am. Chem. Soc. 1986, 108, 6405-6406

(063)

4

433

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. I. Preparation of Chiral Ferrocenylphosphines.

Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, N.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M.

Bull. Chem. Soc. Jpn. 1980, 53, 1138-1151

(027)

5

413

Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones.

Takaya, Y.; Ogasawara, M.; Hayashi, T.; Sakai, M.; Miyaura, N.

J. Am. Chem. Soc. 1998, 120, 5579-5580

(163)

6

344

Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-p-allylrhodium, and Hydroxorhodium Intermediates.

Hayashi, T.; Takahashi, M.; Takaya, Y.; Ogasawara. M.

J. Am. Chem. Soc. 2002, 124, 5052-5058

(201)

7

315

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 8. Palladium-Catalyzed Asymmetric Allylic Amination.

Hayashi, T.; Yamamoto, A.; Ito, Y.; Nishioka, E.; Miura, H.; Yanagi, K.

J. Am. Chem. Soc. 1989, 111, 6301-6311

(094)

8

302

Asymmetric Allylic Substitution and Grignard Cross-Coupling.

Hayashi, T.

In Catalytic Asymmetric Synthesis; Ojima, I., Ed.; VCH Pub: New York, N.Y., 1993; pp 325-365

(R042)

9

269

Asymmetric Synthesis Catalyzed by Transition-Metal Complexes with Functionalized Chiral Ferrocenylphosphine Ligands.

Hayashi, T.; Kumada, M.

Acc. Chem. Res. 1982, 15, 395-401

(R014)

10

266

Chiral Monodentate Phosphine Ligand MOP for Transition-Metal-Catalyzed Asymmetric Reactions.

Hayashi, T.

Acc. Chem. Res. 2000, 33, 354-362

(R064)

11

245

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 2. Nickel- and Palladium-Catalyzed Asymmetric Grignard Cross-Coupling.

Hayashi, T.; Konishi, M.; Fukushima, M.; Mise, T.; Kagotani, M.; Tajika, M.; Kumada, M.

J. Am. Chem. Soc. 1982, 104, 180-186

(040)

12

241

Synthesis of Optically Active 2-(Diarylphosphino)-1,1'-binaphthyls, Efficient Chiral Monodentate Phosphine Ligands.

Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T.

J. Org. Chem. 1993, 58, 1945-1948

(117)

13

240

Modification of Optically Active Ferrocenylphosphine Ligands for Palladium-Catalyzed Asymmetric Allylic Alkylation.

Hayashi, T.; Yamamoto, A.; Hagihara, T.; Ito, Y.

Tetrahedron Lett. 1986, 27, 191-194

(060)

14

239

Togni, A.; Hayashi, T.

Ferrocenes; VCH: Weinheim, 1995

(R049)

15

235

Catalytic Asymmetric Arylation of 2,3-Dihydrofuran with Aryl Triflates.

Ozawa, F.; Kubo, A.; Hayashi, T.

J. Am. Chem. Soc. 1991, 113, 1417-1419

(100)

16

221

Palladium-Catalyzed Asymmetric Arylation of 2,3-Dihydrofuran with Phenyl Triflate. A Novel Asymmetric Catalysis Involving a Kinetic Resolution Process.

Ozawa, F.; Kubo, A.; Matsumoto, Y.; Hayashi, T.; Nishioka, E.; Yanagi, K.; Moriguchi, K.

Organometallics 1993, 12, 4188-4196

(123)

17

214

Optically Active Allylsilanes. 1. Preparation by Palladium-Catalyzed Asymmetric Grignard Cross-Coupling and Anti Stereochemistry in Electrophilic Substitution Reactions.

Hayashi, T.; Konishi, M.; Ito, H.; Kumada, M.

J. Am. Chem. Soc. 1982, 104, 4962-4963

(041)

18

214

A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts: Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition.

Hayashi, T.; Ueyama, K.; Tokunaga, N.; Yoshida, K.

J. Am. Chem. Soc. 2003, 125, 11508-11509

(226)

19

214

Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids and Their Derivatives to Electron Deficient Olefins.

Hayashi, T.

Synlett 2001, 879-887

(R072)

20

213

Chiral (b-Aminoalkyl)phosphines. Highly Efficient Phosphine Ligands for Catalytic Asymmetric Grignard Cross-Coupling.

Hayashi, T.; Konishi, M.; Fukushima, M.; Kanehira, K.; Hioki, T.; Kumada, M.

J. Org. Chem. 1983, 48, 2195-2202

(050)

21

208

Catalytic Asymmetric Synthesis of Optically Active 2-Alkanols via Hydrosilylation of 1-Alkenes with a Chiral Monophosphine-Palladium Catalyst.

Uozumi, Y.; Hayashi, T.

J. Am. Chem. Soc. 1991, 113, 9887-9888

(108)

22

200

Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst.

Uozumi, Y.; Danjo, H.; Hayashi, T.

J. Org. Chem. 1999, 64, 3384-3388

(172)

23

195

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Metal Complexes.

Hayashi, T.

Pure Appl. Chem. 1988, 60, 7-12

(R027)

24

194

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 6. Practical Asymmetric Synthesis of 1,1'-Binaphthyls via Asymmetric Cross-Coupling with a Chiral (Alkoxyalkylferrocenyl)­monophosphine/Nickel Catalyst.

Hayashi, T.; Hayashizaki, K.; Kiyoi, T.; Ito, Y.

J. Am. Chem. Soc. 1988, 110, 8153-8156

(084)

25

186

Catalytic Asymmetric Hydroboration of Styrenes.

Hayashi, T.; Matsumoto, Y.; Ito, Y.

J. Am. Chem. Soc. 1989, 111, 3426-3428

(090)

26

179

C2-Symmetric Bicyclo[2.2.2]octadienes as Chiral Ligands: Their High Performance in Rhodium-Catalyzed Asymmetric Arylation of N-Tosylarylimines.

Tokunaga, N.; Otomaru, Y.; Okamoto, K.; Ueyama, K.; Shintani, R.; Hayashi, T.

J. Am. Chem. Soc. 2004, 126, 13584-13585

(240)

27

168

Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes.

Hayashi, T.; Senda, T.; Ogasawara, M.

J. Am. Chem. Soc. 2000, 122, 10716-10717

(187)

28

164

Stereochemistry of Oxidative Addition of an Optically Active Allyl Acetate to a Palladium(0) Complex.

Hayashi, T.; Hagihara, T.; Konishi, M.; Kumada, M.

J. Am. Chem. Soc. 1983, 105, 7767-7768

(053)

29

164

Rhodium-Catalyzed Asymmetric Arylation of Imines with Organostannanes. Asymmetric Synthesis of Diarylmethylamines.

Hayashi, T.; Ishigedani, M.

J. Am. Chem. Soc. 2000, 122, 976-977

(180)

30

157

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 5. Palladium-Catalyzed Asymmetric Allylation of Active Methine Compounds.

Hayashi, T.; Kanehira, K.; Hagihara, T.; Kumada, M.

J. Org. Chem. 1988, 53, 113-120

(078)

31

156

Stereo- and Regiochemistry in Palladium-Catalyzed Nucleophilic Substitution of Optically Active (E)- and (Z)-Allyl Acetates.

Hayashi, T.; Yamamoto, A.; Hagihara, T.

J. Org. Chem. 1986, 51, 723-727

(061)

32

155

Catalytic Asymmetric Wacker-Type Cyclization.

Uozumi, Y.; Kato, K.; Hayashi, T.

J. Am. Chem. Soc. 1997, 119, 5063-5064

(155)

33

153

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 3. Preparation of Optically Active Allylsilanes by Palladium-Catalyzed Asymmetric Grignard Cross-Coupling.

Hayashi, T.; Konishi, M.; Okamoto, Y.; Kabeta, K.; Kumada, M.

J. Org. Chem. 1986, 51, 3772-3781

(064)

34

152

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): An Effective Catalyst for Cross-Coupling Reaction of a Secondary Alkyl Grignard Reagent with Organic Halides.

Hayashi, T.; Konishi, M.; Kumada, M.

Tetrahedron Lett. 1979, 1871-1874

(022)

35

149

Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates.

Hayashi, T.; Senda, T.; Takaya, Y.; Ogasawara, M.

J. Am. Chem. Soc. 1999, 121, 11591-11592

(177)

36

148

Asymmetric Catalytic Hydrosilylation of Ketones. Preparation of Chiral Ferrocenyl­phosphines as Chiral Ligands.

Hayashi, T.; Yamamoto, K.; Kumada, M.

Tetrahedron Lett. 1974, 4405-4408

(007)

37

148

Optically Active Allylsilanes. 2. High Stereoselectivity in Asymmetric Reaction with Aldehydes Producing Homoallylic Alcohols.

Hayashi, T.; Konishi, M.; Kumada, M.

J. Am. Chem. Soc. 1982, 104, 4963-4965

(042)

38

148

Generation of Tertiary Phosphine-Coordinated Pd(0) Species from Pd(OAc)2 in the Catalytic Heck Reaction.

Ozawa, F.; Kubo, A.; Hayashi, T.

Chem. Lett. 1992, 2177-2180

(114)

39

148

Retention of Regiochemistry of Allylic Esters in Palladium-Catalyzed Allylic Alkylation in the Presence of a MOP Ligand.

Hayashi, T.; Kawatsura, M.; Uozumi, Y.

J. Am. Chem. Soc. 1998, 120, 1681-1687

(161)

40

144

Asymmetric Hydroboration of Styrenes Catalyzed by Cationic Chiral Phosphine-Rhodium(I) Complexes.

Hayashi, T.; Matsumoto, Y.; Ito, Y.

Tetrahedron Asymmetry 1991, 2, 601-612

(106)

41

144

Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complexes.

Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K.

J. Am. Chem. Soc. 1994, 116, 775-776

(128)

42

141

Rhodium-Catalyzed Hydroarylation of Alkynes with Arylboronic Acids: 1,4-Shift of Rhodium from 2-Aryl-1-alkenylrhodium to 2-Alkenylarylrhodium Intermediate.

Hayashi, T.; Inoue, K.; Taniguchi, N.; Ogasawara, M.

J. Am. Chem. Soc. 2001, 123, 9918-9919

(196)

43

138

Iron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing b-Hydrogens.

Nagano, T.; Hayashi, T.

Org. Lett. 2004, 6, 1297-1299

(231)

44

125

Catalytic Asymmetric Arylative Cyclization of Alkynals: Phosphine-Free Rhodium/Diene Complexes as Efficient Catalysts.

Shintani, R.; Okamoto, K.; Otomaru, Y.; Ueyama, K.; Hayashi, T.

J. Am. Chem. Soc. 2005, 127, 54-55

(242)

45

124

Asymmetric Hydrogenation Catalyzed by a Chiral Ferrocenyl­phosphine-Rhodium Complex.

Hayashi, T.; Mise, T.; Mitachi, S.; Yamamoto, K.; Kumada, M.

Tetrahedron Lett. 1976, 1133-1134

(014)

46

119

Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboron Reagents to 5,6-Dihydro-2(1H)-pyridinones. Asymmetric Synthesis of 4-Aryl-2-piperidinones.

Senda, T.; Ogasawara, M.; Hayashi, T.

J. Org. Chem. 2001, 66, 6852-6856

(197)

47

116

Preparation of Optically Active Binaphthylmonophosphines (MOP's) Containing Various Functional Groups.

Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T.

Tetrahedron 1994, 50, 4293-4302

(130)

48

115

Fluorinated Polysilanes. Palladium-Catalyzed Disilane Metathesis, Double Silylation of Acetylenes, and the Stereochemical Course.

Tamao, K.; Hayashi, T.; Kumada, M.

J. Organomet. Chem. 1976, 114, C19-C21

(011)

49

115

High Stereoselectivity in Asymmetric Grignard Cross-Coupling Catalyzed by Nickel Complexes of Chiral (Aminoalkylferrocenyl)phosphines.

Hayashi, T.; Tajika, M.; Tamao, K.; Kumada, M.

J. Am. Chem. Soc. 1976, 98, 3718-3719

(015)

50

115

Regio- and Enantioselective Allylic Alkylation Catalysed by a Chiral Monophosphine-Palladium Complex.

Hayashi, T.; Kawatsura, M.; Uozumi, Y.

Chem. Commun. 1997, 561-562

(154)

51

113

Catalytic Asymmetric Synthesis of Axially Chiral Biaryls by Palladium-Catalyzed Enantioposition-Selective Cross-Coupling.

Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y.

J. Am. Chem. Soc. 1995, 117, 9101-9102

(141)

52

112

Asymmetric Synthesis of b-Hydroxy-a-alkylamino Acids by Asymmetric Aldol Reaction of a-Isocyanocarboxylates Catalyzed by Chiral Ferrocenyl­phosphine-Gold(I) Complexes.

Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.

Tetrahedron 1988, 44, 5253-5262

(080)

53

112

Palladium-Catalyzed Asymmetric Allylic Substitution in Aqueous Media Using Amphiphilic Resin-Supported MOP Ligands.

Uozumi, Y.; Danjo, H.; Hayashi, T.

Tetrahedron Lett. 1998, 39, 8303-8306

(167)

54

112

Rhodium-Catalyzed Asymmetric Addition of Aryl- and Alkenylboronic Acids to Isatins.

Shintani, R.; Inoue, M.; Hayashi, T.

Angew. Chem. Int. Ed. 2006, 45, 3353-3356

(270)

55

110

New Amphiphilic Palladium-Phosphine Complexes Bound to Solid Supports: Preparation and Use for Catalytic Allylic Substitution in Aqueous Media.

Uozumi, Y.; Danjo, H.; Hayashi, T.

Tetrahedron Lett. 1997, 38, 3557-3560

(156)

56

110

Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Reagents to a,b-Unsaturated Esters.

Takaya, Y.; Senda, T.; Kurushima, H.; Ogasawara, M.; Hayashi, T.

Tetrahedron Asymmetry 1999, 10, 4047-4056

(175)

57

108

Erythroselectivity in Addition of g-Substituted Allylsilanes to Aldehydes in the Presence of Titanium Chloride.

Hayashi, T.; Kabeta, K.; Hamachi, I.; Kumada, M.

Tetrahedron Lett. 1983, 24, 2865-2868

(049)

58

108

Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex.

Sawamura, M.; Ito, Y.; Hayashi, T.

Tetrahedron Lett. 1989, 30, 2247-2250

(091)

59

107

Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Design and Preparation of New Efficient Ferrocenylphosphine Ligands.

Ito, Y.; Sawamura, M.; Hayashi, T.

Tetrahedron Lett. 1987, 28, 6215-6218

(072)

60

107

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 10. Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate.

Hayashi, T.; Sawamura, M.; Ito, Y.

Tetrahedron 1992, 48, 1999-2012

(111)

61

106

Preparation of C2-Symmetric Bicyclo[2.2.2]octa-2,5-diene Ligands and Their Use for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids.

Otomaru, Y.; Okamoto, K.; Shintani, R.; Hayashi, T.

J. Org. Chem. 2005, 70, 2503-2508

(245)

62

104

A Chiral (Hydroxyalkylferrocenyl)phosphine Ligand. Highly Stereoselective Catalytic Asymmetric Hydrogenation of Prochiral Carbonyl Compounds.

Hayashi, T.; Mise, T.; Kumada, M.

Tetrahedron Lett. 1976, 4351-4354

(016)

63

104

Homochiral 2,2'-Bis(oxazolyl)-1,1'-binaphthyls as Ligands for Copper(I)-Catalyzed Asymmetric Cyclopropanation.

Uozumi, Y.; Kyota, H.; Kishi, E.; Kitayama, K.; Hayashi, T.

Tetrahedron Asymmetry 1996, 7, 1603-1606

(148)

64

104

Catalytic Asymmetric Reactions via p-Allylpalladium Complexes Coordinated with Chiral Monophosphine Ligands.

Hayashi, T.

J. Organomet. Chem. 1999, 576, 195-202

(R058)

65

101

Asymmetric Aldol Reaction of a-Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of a-Alkylserines.

Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.

Tetrahedron Lett. 1988, 29, 235-238

(075)

66

100

Synthesis and Application of Novel Chiral Phosphino-Oxazoline Ligands with 1,1'-Binaphthyl Skeleton.

Ogasawara, M.; Yoshida, K.; Kamei, H.; Kato, K.; Uozumi, Y.; Hayashi, T.

Tetrahedron Asymmetry 1998, 9, 1779-1787

(164)

67

100

C2-Symmetric Bicyclo[3.3.1]nonadiene as a Chiral Ligand for Rhodium-Catalyzed Asymmetric Arylation of N-(4-Nitrobenzenesulfonyl)arylimines.

Otomaru, Y.; Tokunaga, N.; Shintani, R.; Hayashi, T.

Org. Lett. 2005, 7, 307-310

(243)

68

99

Optically Active Ruthenocenylbis(phosphines): New Efficient Chiral Phosphine Ligands for Catalytic Asymmetric Reactions.

Hayashi, T.; Ohno, A.; Lu, S.-J.; Matsumoto, Y.; Fukuyo, E.; Yanagi, K.

J. Am. Chem. Soc. 1994, 116, 4221-4226

(131)

69

98

Rhodium-Catalyzed Asymmetric 1,4-Addition of 2-Alkenyl-1,3,2-benzodioxaboroles to a,b-Unsaturated Ketones.

Takaya, Y.; Ogasawara, M.; Hayashi, T.

Tetrahedron Lett. 1998, 39, 8479-8482

(168)

70

97

Nickel-Catalyzed Cross-Coupling of Silyl Enol Ethers with Grignard Reagents. Regio- and Stereocontrolled Synthesis of Olefins.

Hayashi, T.; Katsuro, Y.; Kumada, M.

Tetrahedron Lett. 1980, 21, 3915-3918

(031)

71

97

Allylic Substitution in Water Catalyzed by Amphiphilic Resin-Supported Palladium-Phosphine Complexes.

Danjo, H.; Tanaka, D.; Hayashi, T.; Uozumi, Y.

Tetrahedron 1999, 55, 14341-14352

(176)

72

96

Stereochemistry of the Reaction of an Optically Active p-Allylpalladium Complex with Nucleophiles.

Hayashi, T.; Konishi, M.; Kumada, M.

J. Chem. Soc., Chem. Commun. 1984, 107-108

(055)

73

93

Palladium-Phosphine Complex Catalyzed Cross-Coupling Reaction of 1-Methyl-2-pyrrolyl-Magnesium Bromide and -Zinc Chloride with Organic Halides.

Minato, A.; Tamao, K.; Hayashi, T.; Suzuki, K.; Kumada, M.

Tetrahedron Lett. 1981, 22, 5319-5322

(038)

74

93

Rhodium-Catalyzed Asymmetric Addition of Organo-boron and -titanium Reagents to Electron Deficient Olefins.

Hayashi, T.

Bull. Chem. Soc. Jpn. 2004, 77, 13-21

(R085)

75

92

Asymmetric Synthesis of 2-Amino-1-Arylethanols by Catalytic Asymmetric Hydrogenation.

Hayashi, T.; Katsumura, A.; Konishi, M.; Kumada, M.

Tetrahedron Lett. 1979, 425-428

(021)

76

92

Asymmetric Allylic Amination Catalyzed by Chiral Ferrocenylphosphine-Palladium Complexes.

Hayashi, T.; Kishi, K.; Yamamoto, A.; Ito, Y.

Tetrahedron Lett. 1990, 31, 1743-1746

(097)

77

92

Catalytic Asymmetric Arylation of Olefins.

Hayashi, T.; Kubo, A.; Ozawa, F.

Pure Appl. Chem. 1992, 64, 421-427

(R034)

78

91

Chiral Phosphine-Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Maleimides

Shintani, R.; Duan, W.-L.; Nagano, T.; Okada, A.; Hayashi, T.

Angew. Chem. Int. Ed. 2005, 44, 4611-4614

(254)

79

90

Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Compounds Generated in situ from Aryl Bromides.

Takaya, Y.; Ogasawara, M.; Hayashi, T.

Tetrahedron Lett. 1999, 40, 6957-6961

(173)

80

89

Optically Active Cyclic Allylsilanes. Preparation by Asymmetric Hydrosilylation and Anti Stereochemistry in SE' Reactions.

Hayashi, T.; Kabeta, K.; Yamamoto, T.; Tamao, K.; Kumada, M.

Tetrahedron Lett. 1983, 24, 5661-5664

(052)

81

89

Asymmetric Synthesis of threo- and erythro-Sphingosines by Asymmetric Aldol Reaction of a-Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex.

Ito, Y.; Sawamura, M.; Hayashi, T.

Tetrahedron Lett. 1988, 29, 239-240

(076)

82

88

Chiral Norbornadienes as Efficient Ligands for the Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Fumaric and Maleic Compounds.

Shintani, R.; Ueyama, K.; Yamada, I.; Hayashi, T.

Org. Lett. 2004, 6, 3425-3427

(237)

83

87

A Novel Axially Chiral 2,2'-Bipyridine N,N'-Dioxide.@ Its Preparation and Use for Asymmetric Allylation of Aldehydes with Allyl(trichloro)silane as a Highly Efficient Catalyst.

Shimada, T.; Kina, A.; Ikeda, S.; Hayashi, T.

Org. Lett. 2002, 4, 2799-2801

(208)

84

86

Insertion of Alkenes into a Palladium-Acetyl Bond.

Ozawa, F.; Hayashi, T.; Koide, H.; Yamamoto, A.

J. Chem. Soc., Chem. Commun. 1991, 1469-1470

(107)

85

86

Rhodium-Catalyzed Asymmetric Construction of Quaternary Carbon Stereocenters: Ligand-Dependent Regiocontrol in the 1,4-Addition to Substituted Maleimides.

Shintani, R.; Duan, W.-L.; Hayashi, T.

J. Am. Chem. Soc. 2006, 128, 5628-5629

(271)

86

85

Palladium-Assisted Alkylation of Olefins.

Hegedus, L. S.; Williams, R. E.; McGuire, M. A.; Hayashi, T.

J. Am. Chem. Soc. 1980, 102, 4973-4979

(030)

87

84

Asymmetric Hydrosilylation of Olefins Catalyzed by MOP-Palladium Complexes.

Hayashi, T.

Acta Chemica Scandinavica 1996, 50, 259-266

(R050)

88

83

Chiral b-Dimethylaminoalkylphosphines. Highly Efficient Ligands for a Nickel Complex Catalyzed Asymmetric Grignard Cross-Coupling Reaction.

Hayashi, T.; Fukushima, M.; Konishi, M.; Kumada, M.

Tetrahedron Lett. 1980, 21, 79-82

(024)

89

83

J. Am. Chem. Soc. 1987, 109, 7876-7878

(073)

90

83

Palladium-Catalyzed Asymmetric Arylation of 2,3-Dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an Efficient Base.

Ozawa, F.; Kubo, A.; Hayashi, T.

Tetrahedron Lett. 1992, 33, 1485-1488

(110)

91

81

Tetrahedron Lett. 1980, 21, 1871-1874

(028)

92

81

Bull. Chem. Soc. Jpn. 1995, 68, 713-722

(139)

93

80

J. Chem. Soc., Chem. Commun. 1986, 1090-1092

(062)

94

78

Tetrahedron Lett. 1996, 37, 4969-4972

(149)

95

77

J. Org. Chem. 2001, 66, 1441-1449

(188)

96

77

J. Am. Chem. Soc. 2004, 126, 6240-6241

(234)

97

76

Synthesis 1981, 1001-1003

(039)

98

76

J. Org. Chem. 1998, 63, 5071-5075

(165)

99

75

Organometallics 1994, 13, 3237-3243

(137)

100

75

Asymmetric Synthesis, Morrison, J. D., Ed.; Academic Press, 1985; Vol. 5, pp 147-169

(R019)

101

74

Tetrahedron Lett. 1977, 1389-1392

(018)

102

74

Tetrahedron Lett. 1992, 33, 7185-7188

(115)

103

73

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