Papers in press
“Rational Synthesis of 5,10-Diazaporphyrins via Nucleophilic Substitution Reactions of α,α’-Dibromotripyrrin and Dihydrogenation to Give 5,10-Diazachlorins”
M. Umetani, G. Kim, T. Tanaka, D. Kim, A. OsukaJ. Org. Chem., in press
“Excited‐state Aromaticity of Gold(III) Hexaphyrins with Metalation Effect Investigated by Time‐resolved Electronic & Vibrational Spectroscopies”
J. Kim, T. Soya, T. Yoneda, J. Oh, S. Park, M. Lim, A. Osuka, D. KimAngew. Chem. Int. Ed., in press
“Tf2O-mediated Reaction of Alkenyl Sulfoxides with Unprotected Anilines in Flow Microreactors”
A. Baralle, T. Inukai, T. Yanagi, K. Nogi, A. Osuka, A. Nagaki, J. Yoshida, H. YorimitsuChem. Lett., in press
“Cyclophane‐type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18‐Porphyrinyl Dicyanomethyl Diradicals”
B. Adinarayana, K. Kato, D. Shimizu, T. Tanaka, K. Furukawa, A. OsukaAngew. Chem. Int. Ed., in press
“meso-(2-Pyridyl)-boron(III)-subporphyrin: Perimeter Iridium(III) Coordination”
G. Lavarda, D. Shimizu, T. Torres, A. OsukaAngew. Chem. Int. Ed., in press
“Synthesis of Azabenziporphyrinoids by SNAr Reactions”
M. Umetani, T. Tanaka, A. OsukaJ. Porphyrins Phthalocyanines, in press
2019
“Facile synthesis of fluorescent hetero[8]circulene analogues with tunable solubilities and optical properties”
Y. Matsuo, F. Chen, K. Kise, T. Tanaka, A. OsukaChem. Sci., 10, 11006-11012 (2019)
“Singly and Doubly Quinoxaline-fused BIII-Subporphyrins”
K. Kise, A. OsukaChem. Eur. J., 25, 15493-15497 (2019)
“Singly and Doubly Neo-confused Smaragdyrins”
Y. Rao, W. Zhou, L. Xu, M. Zhou, B. Yin, T. Tanaka, A. Osuka, J. SongJ. Am. Chem. Soc., 141, 18836-18844 (2019)
“Phenylene‐bridged Porphyrin meso‐Oxy Radical Dimers”
T. Yamamoto, K. Kato, D. Shimizu, T. Tanaka, A. OsukaChem. Asian J., 14, 4031-4034 (2019)
“Quadrupolar Cyclopenta[hi]aceanthrylene‐based Electron Donor‐Acceptor‐Donor Conjugates: Charge Transfer versus Charge Separation”
C. Schierl, W. Alex, L. M. Mateo, B. Ballesteros, D. Shimizu, A. Osuka, T. Torres, D. M. Guldi, G. BottariAngew. Chem. Int. Ed., 58, 14644-14652 (2019)
“5,20-Diheterohexaphyrins: metal-template-free synthesis and aromaticity switching”
M. Umetani, J. Kim, T. Tanaka, D. Kim, A. OsukaChem. Commun., 55, 10547-10550 (2019)
“ortho-Phenylene Bridged Hybrid Nanorings of 2,5-Pyrrolylenes and 2,5-Thienylenes”
F. Chen, J. Kim, Y. Matsuo, Y. Hong, D. Kim, T. Tanaka, and A. OsukaAsian J. Org. Chem., 8, 994-1000 (2019)
“Electron transfer reactions in sub-porphyrin–naphthyldiimide dyads”
B. Küçüköz, B. Adinarayana, A. Osuka, B. AlbinssonPhys. Chem. Chem. Phys., 21, 16477-16485 (2019)
“Acetylene and trans-Ethylene Bridged BIII-Subporphyrin Dimers”
Y. Bekki, S. Kang, D. Kim, A. OsukaChem. Asian J., 14, 2230-2234 (2019)
“Stable Radical versus Reversible σ-Bond Formation of (Porphyrinyl)dicyanomethyl Radicals”
B. Adinarayana, D. Shimizu, K. Furukawa, A. OsukaChem. Sci., 10, 6007-6012 (2019)
“meta-and para-Phenylenediamine-fused Porphyrin Dimers: Synthesis and Magnetic Interactions in Their Dication Diradicals”
K. Kato and A. OsukaAngew. Chem. Int. Ed., 58, 8546-8590 (2019)
“Synthesis, Structures, and Near‐IR Absorption of Heterole‐fused Earring Porphyrins”
L. Wu, F. Li, Y. Rao, B. Wen, L. Xu, M. Zhou, T. Tanaka, A. Osuka, J. SongAngew. Chem. Int. Ed., 58, 8124-8128 (2019)
“π-Ruthenium Complexes of Hexaphyrins(1.1.1.1.1.1): A Triple Decker Complex Bearing Two Ruthenoarene Units”
A. Nakai, S.-i. Ishida, T. Soya, and A. OsukaAngew. Chem. Int. Ed., 58, 8197-8200 (2019)
“Bis-copper(II) Complex of Triply-linked Corrole Dimer and Its Dication”
S. Ooi, T. Tanaka, T. Ikeue, K. Yamasumi, K. Ueta, D. Shimizu, M. Ishida, H. Furuta, and A. OsukaChem. Asian J., 14, 1771-1776 (2019)
“Internally Bridged Hückel Aromatic [46]Decaphyrins: (Doubly‐Twisted‐Annuleno)Doubly‐Twisted‐Annulene Variants”
T. Soya and A. OsukaChem. Eur. J., 25, 5173-5176 (2019)
“Aminyl Radical Bridged NiII-Porphyrin Dimer: Coordination-Induced Spin-State Switching between Doublet and Sextet States”
D. Shimizu, Y. Ide, T. Ikeue, and A. OsukaAngew. Chem. Int. Ed., 58, 5023-5027 (2019)
“5,20‐Bis(ethoxycarbonyl)‐Substituted Antiaromatic [28]Hexaphyrin and Its Bis‐NiII and Bis‐CuII Complexes”
A. Nakai, J. Kim, D. Kim, and A. OsukaChem. Asian J., 14, 968-971 (2019)
“Synthesis of Meso-Diarylaminocorroles via SNAr Reactions”
K. Ueta, T. Tanaka, and A. OsukaMolecules, 24, 642 (2019)
“Selective Formation of Helical Tetrapyrrin-fused Porphyrins by Oxidation of β-to-β Linked meso-Aminoporphyrin Dimers”
K. Fujimoto, D. Shimizu, T. Mori, Y. Li, M. Zhou, J. Song, and A. OsukaChem. Eur. J., 25, 1711-1715 (2019)
“Stable (BIII-Subporphyrin-5-yl)dicyanomethyl Radicals”
B. Adinarayana, D. Shimizu, and A. OsukaChem. Eur. J., 25, 1706-1710 (2019)
“Aromatic and Antiaromatic Cyclophane-type Hexaphyrin Dimers”
A. Nakai, T. Yoneda, S.-i. Ishida, K. Kato, and A. OsukaChem. Asian J., 14, 256-260 (2019)
“Porphyrin-Stabilized Nitrenium Dication”
K. Fujimoto, D. Shimizu, and A. OsukaChem. Eur. J., 25, 521-525 (2019)
“[n]Cyclo-para-biphenylmethine Polyradicaloids: [n]Annulene Analogs and Unusual Valence Tautomerization”
Y. Ni, M. E. Sandoval-Salinas, T. Tanaka, H. Phan, T. S .Herng, T. Y. Gopalakrishna, J. Ding, A. Osuka, D. Casanova, and J. WuChem, 5, 108-121 (2019)
