- “Triarylporphyrin meso-Oxy Radicals: Remarkable Chemical Stabilities and Oxidation to Oxophlorin π-Cations”
D. Shimizu, J. Oh, K. Furukawa, D. Kim, and A. Osuka
J. Am. Chem. Soc., 137, 15584-15594 (2015). *Hilighted in JACS Spotlights.
- “5,20-Di(pyridin-2-yl)-[28]Hexaphyrin(1.1.1.1.1.1): A Stable Hückel Antiaromatic Hexaphyrin Stabilized by Intramolecular Hydrogen Bonding and Protonation Induced Conformational Twist to Gain Möbius Aromaticity”
K. Naoda, H. Mori, J. Oh, K. H. Park, D. Kim, and A. Osuka
J. Org. Chem., 80, 11726-11733 (2015)
- “Synthesis of [n]Cyclo-5,15-porphyrinylene-4,4'-biphenylenes Displaying Size-dependent Excitation Energy Hopping”
H.-W. Jiang, T. Tanaka, T. Kim, Y. M. Sung, H. Mori, D. Kim, and A. Osuka
Angew. Chem. Int. Ed., 54, 15197-15201 (2015)
- “Peripherally Silylated Porphyrins”
K. Kato, K. Fujimoto, H. Yorimitsu, and A. Osuka
Chem. Eur. J., 21, 13522-13525 (2015)
- “Switching between Aromatic and Antiaromatic 1,3-Phenylene-Strapped [26]- and [28]Hexaphyrins upon Passage to the Singlet Excited State”
Y. M. Sung, J. Oh, W. Kim, H. Mori, A. Osuka, and D. Kim
J. Am. Chem. Soc., 137, 11856-11859 (2015)
- “Singly and Doubly β-to-β Platinum-bridged Porphyrin Dimers and Their Reductive Eliminations”
H.-W. Jiang, T. Tanaka, and A. Osuka
*Selected as a Hot Chemical Science article.(URL)
Chem. Sci., 6, 6102-6105 (2015)
- “Porphyrinylboranes Synthesized via Porphyrinyllithiums”
K. Fujimoto, H. Yorimitsu, and A Osuka
Chem. Eur. J., 21, 11311-11314 (2015)
- “A Stable Organic π-Radical of a Zinc(II)–Copper(I)–Zinc(II) Complex of Decaphyrin”
Y. Tanaka, T. Yoneda, K. Furukawa, T. Koide, H. Mori, T. Tanaka, H. Shinokubo, and A. Osuka
Angew. Chem. Int. Ed., 54, 10908-10911 (2015)
- “Base-Free Palladium-Catalyzed Cross-Coupling of Arylsulfonium Salts with Sodium Tetraarylborates”
D. Vasu, H. Yorimitsu, and A. Osuka
Synthesis, 47, 3286-3291 (2015) *Selected as Cover Picture.
- “Synthesis of A Tetrabenzotetraaza[8]circulene by “Fold-in” Oxidative Fusion Reaction”
F. Chen, Y. S. Hong, S. Shimizu, D. Kim, T. Tanaka, and A. Osuka
Angew. Chem. Int. Ed., 54, 10639-10642 (2015)
- “Transition-Metal-Free Synthesis of Carbazoles and Indoles by an SNAr-Based “Aromatic Metamorphosis“ of Thiaarenes“
M. Bhanuchandra, K. Murakami, D. Vasu, H. Yorimitsu, and A. Osuka
Angew. Chem. Int. Ed., 54, 10234-10238 (2015) *Highlighted in Synfacts.
- “β,β-Diborylated Subporphyrinato Boron(III) Complexes as Useful Synthetic Precursors”
M. Kitano, Y. Okuda, E. Tsurumaki, T. Tanaka, H. Yorimitsu, and A. Osuka
Angew. Chem. Int. Ed., 54, 9275-9279 (2015)
- “Formation of Discrete Ladders and a Macroporous Xerogel Film by the Zipperlike Dimerization of Meso–Meso-Linked Zinc(II) Porphyrin Arrays with Di(pyrid-3-yl)acetylene”
K. Kose, J. Motoyanagi, T. Kusukawa, A. Osuka, and A. Tsuda
Angew. Chem. Int. Ed., 54, 8673-8678 (2015)
- “meso-Aryl [28]Hexaphyrin Silicon Complexes Bearing Various Si-Substituents and 1,16-Dihydrohexaphyrin bis-Chlorosilicon”
S. Ishida, and A. Osuka
Chem. Asian J.,10, 2200-2206 (2015)
- “Observation of Diastereomeric Interconversions of β-Sulfinylsubporphyrins as Evidence for Bowl Inversion”
K. Yoshida and A. Osuka
Chem. Eur. J., 21, 11727-11734 (2015) *Selected as Inside Back Cover.
- “Group 9 Metal Complexes of meso-Aryl-Substituted Rubyrin”
T. Soya and A. Osuka
Chem. Eur. J., 21, 10639-10644 (2015) *Selected as Cover Picture.
- “Peripherally Hexasulfanylated Subporphyrins”
K. Yoshida and A. Osuka
Chem. Asian J., 10, 1526-1534 (2015)
- “Palladium-Assisted “Aromatic Metamorphosis” of Dibenzothiophenes into Triphenylenes”
D. Vasu, H. Yorimitsu, and A. Osuka
Angew. Chem. Int. Ed., 54, 7162-7166 (2015)
- “Stable [48]-. [50]-, and [52]Dodecaphyrins(1.1.0.1.1.0.1.1.0.1.1.0): The Largest Hückel Aromatic Molecules”
T. Soya, W. Kim, D. Kim, and A. Osuka
Chem. Eur. J., 21, 8341-8346 (2015)
*Selected as Inside Back Cover.
Highlighted in ChemistryViews and 有機化学美術館・分館.
Selected as C&EN’s Molecules Of The Year
- “Reversal of Hückel (anti)aromaticity in the lowest triplet states of hexaphyrins and spectroscopic evidence for Baird's rule”
Y. M. Sung, M.-C. Yoon, J. M. Lim, H. Rath, K. Naoda, A. Osuka, and D. Kim
Nat. Chem., 7, 418-422 (2015)
- “Tetracoordinate silicon complexes of 1,2-bis(indol-2-yl)benzene as blue-emitting dyes in the solid state”
T. Tanaka, and A. Osuka
Chem. Commun., 51, 8123-8125 (2015)
- “meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and A Stable meso-Oxy Radical”
D. Shimizu, J. Oh, K. Furukawa, D. Kim, and A. Osuka
Angew. Chem. Int. Ed., 54, 6613-6617 (2015)
- “meso,β-Oligohaloporphyrins as Useful Synthetic Intermediates of Diphenylamine-Fused Porphyrin and meso-to-meso β-to-β Doubly Butadiyne-Bridged Diporphyrin ”
N. Fukui, H. Yorimitsu, and A. Osuka
Angew. Chem. Int. Ed., 54, 6311-6314 (2015)
- “meso-Free Corroles: Syntheses, Structures, Properties, and Chemical Reactivities”
S. Ooi, T. Yoneda, T. Tanaka, and A. Osuka
Chem. Eur. J., 21, 7772-7779 (2015)
- “Bismetal Complexes of 5,20-Bis(5-formyl-2-pyrrolyl)-[26]hexaphyrin(1.1.1.1.1.1) Exhibiting Strong Near-Infrared Region Absorptions”
H. Mori, and A. Osuka
Chem. Eur. J., 21, 7007-7011 (2015)
- “Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines”
K. Gao, H. Yorimitsu, and A. Osuka
Eur. J. Org. Chem., 2015, 2678-2682 (2015)
- “Palladium-Catalyzed Zinc-Amide-Mediated C–H Arylation of Fluoroarenes and Heteroarenes with Aryl Sulfides”
S. Otsuka, H. Yorimitsu, and A. Osuka
Chem. Eur. J., 21, 14703-14707 (2015) *Selected as Inside Cover.
- “A Möbius Aromatic [28]Hexaphyrin Bearing a Diethylamine Group: A Rigid but Smooth Conjugation Circuit”
T. Higashino, T. Soya, W. Kim, D. Kim, and A. Osuka
Angew. Chem. Int. Ed., 54, 5456-5459 (2015)
- “Dimeric 1:2 Adduct of β,β'-Bis(diphenylphosphino)porphyrin with Silver(I) Chloride”
K. Fujimoto, H. Yorimitsu, and A. Osuka
J. Pophyrins Phthalocyanines, 19, 171-174 (2015)
- “Cyclic 2,12-Porphyrinylene Nanorings As a Porphyrin Analogue of Cycloparaphenylenes”
H.-W. Jiang, T. Tanaka, H. Mori, K. H. Park, D. Kim, and A. Osuka
J. Am. Chem. Soc., 137, 2219-2222 (2015)
- “Fused Corrole Dimers Interconvert between Nonaromatic and Aromatic States through Two-electron Redox Reactions”
S. Ooi, T. Tanaka, K. H. Park, S. Lee, D. Kim, and A. Osuka
Angew. Chem. Int. Ed., 54, 3107-3111 (2015)
- “5,20-Bis(α-oligothienyl)-substituted [26]Hexaphyrins Possessing Electronic Circuits Strongly Perturbed by meso-Oligothienyl Substituents”
H. Mori, M. Suzuki, W. Kim, D. Kim and A. Osuka
Chem. Sci., 6, 1696-1700 (2015)
- “meso-meso Linked Porphyrin–[26]Hexaphyrin–Porphyrin Hybrid Arrays and Their Triply Linked Tapes Exhibiting Strong Absorption Bands in NIR Region”
H. Mori, T. Tanaka, S. Lee, J. M. Lim, D. Kim, and A. Osuka
J. Am. Chem. Soc., 137, 2097-2106 (2015)
- “Nickel-NHC-catalyzed Cross-coupling of 2-Methylsulfanylbenzofurans with Alkyl Grignard Reagents”
A. Baralle, S. Otsuka, V. Guérin, K. Murakami, H. Yorimitsu, and A. Osuka
Synlett, 26, 327-330 (2015)
- “Subporphyrinato Boron(III) Hydrides”
E. Tsurumaki, J. Sung, D. Kim, and A. Osuka
J. Am. Chem. Soc., 137, 1056-1059 (2015)*Highlighted in Nature Chemistry.
- “Palladium-Catalyzed [3+2] Annulation of meso-Bromoporphyrin with Silylacetylenes and Desilylation of 8a-Silyl-7,8-dehydropurpurin”
N. Fukui, S. Arai, H. Shinokubo, H. Yorimitsu, and A. Osuka
Heterocycles, 90, 252-260 (2015)
- “Synthesis and Characterization of cis-A2B-type meso-Triaryl Substituted Corroles”
S. Ooi, T. Tanaka, and A. Osuka
Eur. J. Org. Chem., 2015, 130-134 (2015)
- “NiII Metalations of [40]- and [42]Nonaphyrins(1.1.1.1.1.1.1.1.1): The Largest Doubly Twisted Hückel Antiaromatic Molecule”
T. Soya, K. Naoda, and A. Osuka
Chem. Asian J., 10, 231-238 (2015)
- “Activator-Free Palladium-Catalyzed Silylation of Aryl Chlorides with Silylsilatranes”
Y. Yamamoto, H. Matsubara, K. Murakami, H. Yorimitsu, and A. Osuka
Chem. Asian J., 10, 219-224 (2015)