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京都大学 大学院理学研究科 化学専攻 有機合成化学研究室
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研究実績/論文発表(年度毎)

2013
Development of Synthetic Transformations by Control of Acid-catalyzed Reactions of Diazocarbonyl Compounds.
T. Hashimoto, K. Maruoka, Bull. Chem. Soc. Jpn., 86, 1217-1230 (2013).

Chiral Organotin Hydride Catalyzed Enantioselective Radical Cyclization of Aldehydes.
S. Shirakawa, A. Usui, S. B. J. Kan, K. Maruoka, Asian J. Org. Chem., 2, 916-919 (2013).

Kinetic Resolution of Axially Chiral 2-Amino-1,1'-Biaryls by Phase-Transfer-Catalyzed N-Allylation.
S. Shirakawa, X. Wu, K. Maruoka, Angew. Chem. Int. Ed., 52, 14200-14203 (2013).

Metal-Free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine.
T. Kano, F. Shirozu, K. Maruoka, J. Am. Chem. Soc., 135, 18036-18039 (2013). (Highlighted inSYNFACTS, 207 (2014))

In Situ Assembled Boronate Ester Assisted Chiral Carboxylic Acid Catalyzed Asymmetric Trans-Aziridinations.
T. Hashimoto, A. O. Galvez, K. Maruoka, J. Am Chem. Soc., 135, 17667-17670 (2013). (Highlighted inSYNFACTS, 202 (2014))

Reactions Triggered by Lewis Acidic Organoaluminum Species.
Y. Naganawa, K. Maruoka, Top. Organomet. Chem., 41, 187-214 (2013).

Axially Chiral Dicarboxylic Acid Catalyzed Activation of Quinone Imine Ketals: Enantioselective Arylation of Enecarbamates.
T. Hashimoto, H. Nakatsu, Y. Takiguchi, K. Maruoka, J. Am. Chem. Soc., 135, 16010-16013 (2013).

Phase-Transfer-Catalyzed Asymmetric Synthesis of Axially Chiral Anilides.
K. Liu, X. Wu, S. B. J. Kan, S. Shirakawa, K. Maruoka, Chem. Asian J., 8, 3214-3221 (2013).

Organocatalytic Asymmetric Synthesis of Propargylamines with Two Adjacent Stereocenters: Mannich-Type Reactions of In Situ Generated C-Alkynyl Imines with β-Keto Esters.
T. Kano, T. Yurino, K. Maruoka, Angew. Chem. Int. Ed., 52, 11509-11512 (2013). (Highlighted inSYNFACTS, 1233 (2013))

Production at the Curie Level of No-carrier-added 6-18F-fluoro-L-dopa.
L. C. Libert, X. Franci, A. R. Plenevaux, T. Ooi, K. Maruoka, A. J. Luxen, C. F. Lemaire, J. Nucl. Med., 54, 1154-1161 (2013).

Catalytic Asymmetric Three-component 1,3-Dipolar Cycloaddition of Aldehydes, Hydrazides, and Alkynes.
T. Hashimoto, Y. Takiguchi, K. Maruoka, J. Am. Chem. Soc., 135, 11473-11476 (2013). (Highlighted inSYNFACTS, 1049 (2013))

Site-Selective Oxidation of Unactivated C(sp3)-H Bonds with Hypervalent Iodine(III) Reagents.
S. A. Moteki, A. Usui, T. Zhang, C. R. Solorio-Alvarado, K. Maruoka, Angew. Chem. Int. Ed., 52, 8657-8660 (2013). (Selected as a VIP)

Contribution of Cage-Shaped Structure of Physalins to Their Mode of Action in Inhibition of NF-κB Activation.
M. Ozawa, M. Morita, G. Hirai, S. Tamura, M. Kawai, A. Tsuchiya, K. Oonuma, K. Maruoka, M. Sodeoka, ACS Med. Chem. Lett., 4, 730-735 (2013).

Unusual anti-Selective Asymmetric Conjugate Addition of Aldehydes to Nitroalkenes Catalyzed by a Biphenyl-based Chiral Secondary Amine.

T. Kano, H. Sugimoto, O. Tokuda, K. Maruoka, Chem. Commun., 49, 7028-7030 (2013). (Cover Picture)

Design of Chiral Bifunctional Quaternary Phosphonium Bromide Catalysts Possessing an Amide Moiety.
S. Shirakawa, T. Tokuda, A. Kasai, K. Maruoka, Org. Lett., 15, 3350-3353 (2013).

Development of Axially Chiral Dicarboxyiic Acta Catalyzed Asymmetric Transformations.
T. Hashimoto, K. Maruoka, Yuki Gosei Kagaku Kyokaishi, 71, 472-479 (2013).

Construction of a Chiral Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 2-Arylcyclohexanones under Phase-Transfer Conditions.
T. Kano, Y. Hayashi, K. Maruoka, J. Am. Chem. Soc., 135, 7134-7137 (2013). (Most Read Articles)(Highlighted in SYNFACTS, 900 (2013))

Acid-Catalyzed in Situ Generation of Less Accessible or Unprecedented N-Boc Imines from N-Boc Aminals.
T. Kano, T. Yurino, D. Asakawa, K. Maruoka, Angew. Chem. Int. Ed., 52, 5532-5534 (2013). (Highlighted in SYNFACTS, 790 (2013))

Efficient Approach for the Design of Effective Chiral Quaternary Phosphonium Salts in Asymmetric Conjugate Additions.
S. Shirakawa, A. Kasai, T. Tokuda, K. Maruoka, Chem. Sci., 4, 2248-2252 (2013).

Phase-Transfer-Catalyzed Asymmetric Conjugate Cyanation of Alkylidenemalonates with KCN in the Presence of a Bronsted Acid Additive.
Y. Liu, S. Shirakawa, K. Maruoka, Org. Lett., 15, 1230-1233 (2013). (Highlighted in SYNFACTS, 553 (2013))

Phase-transfer Catalyzed Asymmetric Synthesis of Tetrasubstituted Allenes.
T. Hashimoto, K. Sakata, F. Tamakuni, M. J. Dutton, and K. Maruoka, Nature Chem., 5, 240-244 (2013).

Recent Developments in Asymmetric Phase-Transfer Reactions.
S. Shirakawa, K. Maruoka, Angew. Chem. Int. Ed., 52, 4312-4348 (2013).

Unique Properties of Chiral Biaryl-Based Secondary Amine Catalysts for Asymmetric Enamine Catalysis.
T. Kano, K. Maruoka, Chem. Sci., 4, 907-915 (2013). (Most Downloaded Articles)

One-Pot Cross Double-Mannich Reaction of Acetaldehyde Catalyzed by a Binaphthyl-Based Amino Sulfonamide.
T. Kano, R. Sakamoto, Y. Yamaguchi, K. Itoh, K. Maruoka, Chem. Comm., 49, 1118-1120 (2013). (Most Downloaded Articles)

Stereoselective Synthesis of Cyclic Amino Acids via Asymmetric Phase-Transfer Catalytic Alkylation.
T. Kano, T. Kumano, R. Sakamoto, K. Maruoka, Org. Biomol. Chem., 11, 271-278 (2013). (Most Downloaded Articles)(Cover Picture)