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京都大学 大学院理学研究科 化学専攻 有機合成化学研究室
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研究実績/論文発表(年度毎)

2016
[2+2] Photocycloadditions between the Carbon-Nitrogen Double Bonds of Imines and Carbon-Carbon Double Bonds
R. Sakamoto, T. Inada, S. Sakurai, K. Maruoka, Org. Lett., 18, 6252-6255 (2016). (Highlighted in SYNFACTS2017, 240)

Rate Acceleration of Solid-Liquid Phase-Transfer Catalysis by Rotor-Stator Homogenizer
T. Kano, Y. Aota, K. Maruoka, Adv. Synth. Catal., 358, 2996-2999 (2016).

Design of Bifunctional Quaternary Phosphonium Salt Catalysts for CO2 Fixation Reaction with Epoxides under Mild Conditions
S. Liu, N. Suematsu, K. Maruoka, S. Shirakawa, Green Chem., 18, 4611-4615 (2016).

Hydrogen-Bonding Catalysis of Tetraalkylammonium Salts in an Aza-Diels-Alder Reaction
Y. Kumatabara, S. Kaneko, S. Nakata, S. Shirakawa, K. Maruoka, Chem. Asian J., 11, 2126-2129 (2016).

Efficient Generation of Perfluoroalkyl Radicals from Sodium Perfluoroalkanesulfinates and a Hypervalent Iodine(III) Reagent: Mild, Metal-free Synthesis of Perfluoroalkylated Organic Molecules
R. Sakamoto, H. Kashiwagi, S. Selmadurai, S. A. Moteki, K. Maruoka, Org. Biomol. Chem., 14, 6417-6421 (2016).

A Bulky Thiyl-Radical Catalyst for the [3+2] Cyclization of N-Tosyl Vinylaziridines and Alkenes
T. Hashimoto, K. Takino, K. Hato, K. Maruoka, Angew. Chem. Int. Ed., 55, 8081-8085 (2016).

N-Boc-Aminals as Easily Accessible Precursors for Less Accessible N-Boc-Imines: Facile Synthesis of Optically Active Propargylamine Derivatives Using Mannich-Type Reactions
T. Yurino, Y. Aota, D. Asakawa, T. Kano, K. Maruoka, Tetrahedron, 72, 3687-3700 (2016).

A Chiral Electrophilic Selenium Catalyst for Highly Enantioselective Oxidative Cyclization
Y. Kawamata, T. Hashimoto, K. Maruoka, J. Am. Chem. Soc., 138, 5206-5209 (2016).

Diastereoselective Radical Hydroacylation of Alkylidenemalonates with Aliphatic Aldehydes Initiated by Photolysis of Hypervalent Iodine(III) Reagents
S. Selmadurai, R. Sakamoto, K. Maruoka, Chem. Eur. J., 22, 6552-6555 (2016).

Synthesis of N-Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with N-Boc-Aminals and Their Oxidation to N-Boc-Ketimines
T. Kano, R. Kobayashi, K. Maruoka, Org. Lett., 18, 276-279 (2016). (Highlighted in SYNFACTS2016, 292)

Efficient Photolytic C–H Bond Functionalization of Alkylbenzene with Hypervalent Iodine(III) Reagent
R. Sakamoto, T. Inada, S. Selmadurai, S. A. Moteki, K. Maruoka, Chem. Commun., 52, 3758-3761 (2016).

Catalytic Asymmetric Synthesis of Axially Chiral 2-Amino-1,10-Biaryl Compounds by Phase-Transfer-Catalyzed Kinetic Resolution and Desymmetrization
S. Shirakawa, X. Wu, S. Liu, K. Maruoka, Tetrahedron, 72, 5163-5171 (2016).