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京都大学 大学院理学研究科 化学専攻 有機合成化学研究室
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研究実績/論文発表(年度毎)

2017
Chiral Amine-Catalyzed Asymmetric Conjugate Addition of Aldehydes to α-Phenylselenoenones as Formal Z-Allylating Agents
T. Kano, H. Maruyama, C. Homma, K. Maruoka, Chem. Commun., in print.

Asymmetric Synthesis of Less Accessible α-Tertiary Amines from Alkynyl Z-Ketimines
T. Kano, Y. Aota, K. Maruoka, Angew. Chem. Int. Ed., in print.

Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation
M. Shimogaki, H. Maruyama, S. Tsuji, C. Homma, T. Kano, K. Maruoka, J. Org. Chem., 82, 12928-12932 (2017).

The Direct C-​H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy Ligands
R. Sakamoto, H. Kashiwagi, K. Maruoka, Org. Lett., 19, 5126-5129 (2017).

Hypervalent Iodine(III) Catalyzed Radical Hydroacylation of Chiral Alkylidenemalonates with Aliphatic Aldehydes under Photolysis
S. Selvakumar, Q.-K. Kang, N. Arumugam, A. I. Almansour, R. S. Kumar, K. Maruoka, Tetrahedron, 73, 5841-5846 (2017).

Hypervalent Iodine Mediated Chemoselective Iodination of Alkynes
Y. Liu, D. Huang, J. Huang, K. Maruoka, J. Org. Chem., 82, 11865-11871 (2017).

In-​Situ Generation of N-​Boc-​Protected Alkenyl Imines: Controlling the E​/Z Geometry of Alkenyl Moieties in the Mukaiyama-​Mannich Reaction
J.-F. Bai, H. Sasagawa, T. Yurino, T. Kano, K. Maruoka, Chem. Commun., 53, 8203-8206 (2017).


Catalyst-Controlled, Enantioselective and Diastereodivergent Conjugate Addition of Aldehydes to Electron-Deficient Olefins

S. B. J. Kan, H. Maruyama, M. Akakura, T. Kano, K. Maruoka, Angew. Chem. Int. Ed., 56, 9487-9491 (2017).
(Highlighted in SYNFACTS, 2017, 985)

Alkylsilyl Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides and Arylamines
R. Sakamoto, S. Sakurai, K. Maruoka, Chem. Eur. J., 23, 9030-9033 (2017).

Practical Synthesis of Two Different Pseudoenantiomeric Organocatalysts with cis-Cyclohexanediamine Structure from a Common Chiral Source
H.-J. Lee, S. A. Moteki, N. Arumugam, A. I. Almansour, R. S. Kumar, Y. Liu, K. Maruoka, Asian J. Org. Chem., 6, 1226-1230 (2017).

Bis(trialkylsilyl) Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides
R. Sakamoto, S. Sakurai, K. Maruoka, Chem. Commun., 53, 6484-6487 (2017).

In situ Generation of less Accessible Boc-Imines from Aldehydes: Construction of a Quaternary Carbon by the Mannich Reaction or Unprecedented Aldol Reaction
T. Kano, C. Homma, K. Maruoka, Org. Biomol. Chem., 15, 4527-4530 (2017). (Highlighted in SYNFACTS2017, 873)

Practical Synthesis of Both Enantiomeric Amino Acid, Mannich, and Aldol Derivatives by Asymmetric Organocatalysis
Y. Liu, N. Arumugam, A. I. Almansour, R. S. Kumar, K. Maruoka, Chem. Rec., 17, 1059-1069 (2017).

Phase-Transfer Catalyzed Asymmetric Synthesis of α,β-Unsaturated γ,γ-Disubstituted γ-Lactams
A. Arlt, H. Toyama, K. Takada, T. Hashimoto, K. Maruoka, Chem. Commun., 53, 4779-4782 (2017).

Chiral Tertiary Sulfonium Salts as Effective Catalysts for Asymmetric Base-Free
Neutral Phase-Transfer Reactions
S. Liu, K. Maruoka, S. Shirakawa, Angew. Chem. Int. Ed., 56, 4819-4823 (2017).

A New Strategy for Organocatalyzed Asymmetric Synthesis of BINOL Derivatives
S. Shirakawa, K. Maruoka, Chem, 2, 329-331 (2017).

Hydrogen-Bonding Catalysis of Sulfonium Salts
S. Kaneko, Y. Kumatabara, S. Shimizu, K. Maruoka, S. Shirakawa, Chem. Commun., 53, 119-122 (2017).

Synthesis of the Right-Side Structure of Type B Physalins
M. Morita, S. Kojima, M. Ohkubo, H. Koshino, D. Hashizume, G. Hirai, K. Maruoka, M. Sodeoka, Isr. J. Chem., 57, 309-318 (2017).