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京都大学 大学院理学研究科 化学専攻 有機合成化学研究室
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研究実績/論文発表(年度毎)

2018
Design of Efficient Chiral Bifunctional Phase-Transfer Catalysts Possessing an Amino Functionality for Asymmetric Aminations
S. Paria, Q. Kang, M. Hatanaka, K. Maruoka, ACS Catal., in press.

The Radical Acylarylation of N-Arylacrylamides with Aliphatic Aldehydes Using the Photolysis of Hypervalent Iodine(III) Reagents
R. Sakamoto, N. Hirama, K. Maruoka, Org. Biomol. Chem., 16, 5412-5415 (2018).

Enantioselective Alkylation of N-Arylhydrazones Derived from α-Keto Esters and Isatin Derivatives through Asymmetric Phase-Transfer Catalysis
Q.-K. Kang, S. Selvakumar, N. Arumugam, A. I. Almansour, R. S. Kumar, K. Maruoka, Chemistry–Asian J., 13, 1780-1783 (2018).

Synthesis of 1-Aminoindenes through Aza-Prins-Type Cyclization
J.-F. Bai, K. Yasumoto, T. Kano, K. Maruoka, Chemistry–Eur. J., 24, 10320-10323 (2018).

BF3-Catalyzed Synthesis of Cyclic Carbamates from Boc-Protected Aminals and Alkynes
T. Kano, K. Yasumoto, K. Maruoka, Asian J. Org. Chem., 7, 1575-1578 (2018).

Phase-transfer-catalysed Asymmetric Synthesis of 2,2-Disubstituted 1,4-Benzoxazin-3-ones
M. Pawliczek, Y. Shimazaki, H. Kimura, K. M. Oberg, S. Zakpur, T. Hashimoto, K. Maruoka, Chem. Commun., 54, 7078-7080 (2018).

Transition-Metal-Free Direct C-H Silylation of Electron-Deficient Heteroarenes with Hydrosilanes via a Radical Mechanism
R. Sakamoto, B.-N. Nguyen, K. Maruoka, Asian J. Org. Chem., 7, 1085-1088 (2018).

Practical Synthesis of Four Different Pseudoenantiomeric Organocatalysts with Both Cis- and Trans-Substituted 1,2-Cis-cyclohexanediamine Structures from a Common Intermediate
H.-J. Lee, N. Arumugam, A. I. Almansour, R. S. Kumar, K. Maruoka, Tetrahedoron, 74, 5263-5269 (2018).

Indanol-Based Chiral Organoiodine Catalysts for Enantioselective Hydrative Dearomatization
T. Hashimoto, Y. Shimazaki, Y. Omatsu, K. Maruoka, Angew. Chem. Int. Ed., 57, 7200-7204 (2018).

A Synthetic Route to Sodium α-​Aminoalkanesulfinates and Their Application in the Generation of α-​Aminoalkyl Radicals for Radical Addition Reactions
R. Sakamoto, T. Yoshii, H. Takada, K. Maruoka, Org. Lett., 20, 2080-2083 (2018).

Catalyst-​Controlled Diastereoselectivity Reversal in the Formation of Dihydropyrans
T. Kano, H. Maruyama, C. Homma, K. Maruoka, Chem. Commun., 54, 3496-3499 (2018).

Copper-​Catalyzed C(sp)​-​C(sp3) Coupling of Terminal Alkynes with Alkylsilyl Peroxides via a Radical Mechanism
R. Sakamoto, T. Kato, S. Sakurai, K. Maruoka, Org. Lett., 20, 1400-1403 (2018).

Alkylative Kinetic Resolution of Vicinal Diols under Phase-​Transfer Conditions: A Chiral Ammonium Borinate Catalysis
M. Pawliczek, T. Hashimoto, K. Maruoka, Chem. Sci., 9, 1231-1235 (2018).

Chiral Amine-Catalyzed Asymmetric Conjugate Addition of Aldehydes to α-Phenylselenoenones as Formal Z-Allylating Agents
T. Kano, H. Maruyama, C. Homma, K. Maruoka, Chem. Commun., 54, 176-179 (2018).