研究成果/ Publications

  • 原著論文 / Original Article
  • 総説論文 / Review Article


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2024

Methoxydioxasilepane: A Versatile and Stable Synthetic Precursor of Trimethoxysilane

Kenshiro Hitoshio, Takuto Morinaga, Ryohei Sahashi, Shinya Goshona, Hiroki Yamagishi, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*

Synthesis 2024, in Press.

DOI: 10.1055/a-2408-7577

Aryl Silyl Ethers Enable Preferential Ar-O bond Cleavage in Reductive Generation of Aryllithium Species

Daiki Asai, Ziwei Zhang, Fumiya Takahashi, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*

JACS Au 2024, 4, 3118-3124.

DOI: 10.1021/jacsau.4c00448

Synthesis of unsymmetrical dialkoxydiarylsilanes and diarylsilanediols from tetraalkoxysilane having a dioxasilepane unit

Kenshiro Hitoshio, Hiroki Maeda, Kento Teranishi, Jun Shimokawa*, and Hideki Yorimitsu*

Chem. Commun. 2024, 60, 7339-7342.

DOI: 10.1039/d4cc02051k

Sodium-Mediated Reductive anti-Dimagnesiation of Diarylacetylenes with Magnesium Bromide

Haruka Yamaguchi, Fumiya Takahashi, Takashi Kurogi and Hideki Yorimitsu*

Synthesis 2024, in Press.

DOI: 10.1055/a-2326-6416


Arylation of benzazoles at the 4 positions by activation of their 2-methylsulfinyl groups

Ryota Wakabayashi, Shuo Wang, Takashi Kurogi and Hideki Yorimitsu*

Chem. Commun. 2024, 60, 6166-6169.

DOI: 10.1039/d4cc01918k


Reductive anti-Dizincation of Arylacetylenes

Haruka Yamaguchi, Fumiya Takahashi, Takashi Kurogi, and Hideki Yorimitsu*

Chem. Asian. J. 2024, 19, e202400384.

DOI: 10.1002/asia.202400384

Cover Profile


[1,2]-Retro-Brook Rearrangement Induced by Electrochemical Reduction of Silyl Enolates

Ban Kinoshita, Saki Maejima, Yuta Niki, Koichi Mitsudo, Seiji Suga, and Hideki Yorimitsu*

Bull. Chem. Soc. Jpn. 2024, 97, uoae038.

DOI: 10.1093/bulcsj/uoae038


Sodium-Mediated Reductive C–C Bond Cleavage Assisted by Boryl Groups

Mizuki Fukazawa, Fumiya Takahashi, Takashi Kurogi, and Hideki Yorimitsu*

Chem. Asian J. 2024, 19, e202400100.

DOI: 10.1002/asia.202400100


Regioselectivity in the sulfonium-mediated arylation reactions of 2-substituted phenols with benzothienyl sulfoxide

Ryota Wakabayashi, Mizuki Fukazawa, Takashi Kurogi, and Hideki Yorimitsu*

Bull. Chem. Soc. Jpn. 2024, 97, uoae002.

DOI: 10.1093/bulcsj/uoae002


Reductive stereo- and regiocontrolled boryllithiation and borylsodiation of arylacetylenes using flow microreactors

Yiyuan Jiang, Takashi Kurogi, and Hideki Yorimitsu*

Nat. Synth. 2024, 3, 192-201.

DOI: 10.1038/s44160-023-00439-8

プレスリリース Synthesis in flow Chem-Stationスポットライトリサーチ


Regioselective anti-Silyllithiation of Propargylic Amines

Tomohiko Sato, Somnath N. Karad, Jun Shimokawa*, and Hideki Yorimitsu*

Synlett 2024, 35, 419-422.

DOI: 10.1055/a-2047-8456


Regioselective Anti-Silyllithiation of Propargylic Alcohols

Somnath N. Karad, Hayate Saito, Jun Shimokawa*, and Hideki Yorimitsu*

J. Org. Chem. 2024, 89, 3677-3683. (Featured Article)

DOI: 10.1021/acs.joc.2c01795


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Review

Utilization of Silanols in Transition Metal-Catalyzed Organic Synthesis

Hiroki Yamagishi, Jun Shimokawa,* and Hideki Yorimitsu*

ACS Catal. 2023, 13, 7472-7487.

DOI: 10.1021/acscatal.3c01504


Aromatic Metamorphosis of Thiophenes: Replacing Endocyclic Sulfur with a Different Atom or Group of Atoms

Hideki Yorimitsu

Phosphorus Sulfur Silicon Relat. Elem. 2023, 198, in press.

DOI: 10.1080/10426507.2023.2190978


Sulfonium-aided coupling of aromatic rings via sigmatropic rearrangement

Hideki Yorimitsu* and Gregory J. P. Perry*

Proc. Jpn. Acad., Ser. B. 2022, 98, 190-205.

DOI: 10.2183/pjab.98.012


Sulfur(IV) in Transition-Metal-Free Cross-Couplings for Biaryl Synthesis

Gregory J. P. Perry* and Hideki Yorimitsu*

ACS Sustainable Chem. Eng. 2022, 10, 2569-2586.

DOI: 10.1021/acssuschemeng.1c08673


シグマトロピー転位を活用するビアリール合成の新展開
Recent Development of Biaryl Synthesis through Sigmatropic Rearrangement

Tomoyuki Yanagi and Hideki Yorimitsu*

J. Synth. Org. Chem. Jpn. 2021, 79, 427-438.

DOI: 10.5059/yukigoseikyokaishi.79.427


Catalytic Transformations of Sulfonium Salts via C-S Bond Activation

Hideki Yorimitsu*

Chem. Rec. 2021, 3356-3369.

DOI: 10.1002/tcr.202000172


Electron injection for aromatic metamorphosis of indole

Hideki Yorimitsu*

J. Chin. Chem. Soc. 2021, 68, 536-540.

DOI: 10.1002/jccs.202000369


Catalytic C–H Arylation of Tetrathiafulvalenes for the Synthesis of Functional Materials

Hideki Yorimitsu*, Aya Yoshimura, Yohji Misaki

Synthesis 2020, 52, 3326.

DOI: 10.1055/s-0040-1707256


Carbon–Carbon Bond Cleavage at Allylic Positions: Retro-allylation and Deallylation

Keisuke Nogi, and Hideki Yorimitsu*

Chem. Rev. 2021, 121, 345.

DOI: 10.1021/acs.chemrev.0c00157


Catalytic Carbonylation and Carboxylation of Organosulfur Compounds via C–S cleavage

Keisuke Nogi*, and Hideki Yorimitsu*

Chem. Asian J. 2020, 15, 441-449.

DOI: 10.1002/asia.201901644


Ring-expanding and Ring-opening Transformations of Benzofurans and Indoles with Introducing Heteroatoms

Hayate Saito, and Hideki Yorimitsu*

Chem. Lett. 2019, 48, 1019–1028.

DOI: 10.1246/cl.190393


Catalytic inter- and intramolecular coupling of aryl sulfones

Fumiya Takahashi, Keisuke Nogi, and Hideki Yorimitsu*

Phosphorus Sulfur Silicon Relat. Elem. 2019, 194, 742–745.

DOI: 10.1080/10426507.2019.1603232


Recent development of ortho-C–H functionalization of aryl sulfoxides through [3,3] sigmatropic rearrangement

Tomoyuki Yanagi, Keisuke Nogi, and Hideki Yorimitsu*

Tetrahedron Lett. 2018, 59, 2951-2959.

DOI: 10.1016/j.tetlet.2018.06.055


C–S Bond Activation

Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*

Top. Curr. Chem. 2018, 376, 13.

DOI: 10.1007/s41061-018-0190-7


Cascades of Interrupted Pummerer Reaction-Sigmatropic Rearrangement

Hideki Yorimitsu*

Chem. Rec. 2017, 17, 1156–1167.

DOI: 10.1002/tcr.201700017


Aromatic metamorphosis: conversion of an aromatic skeleton into a different ring system

Keisuke Nogi, and Hideki Yorimitsu*

Chem. Commun. 2017, 53, 4055–4065.

DOI: 10.1039/C7CC00078B

Highlighted as Cover Picture.

Cross-coupling of Aryl Sulfides Powered by N-Heterocyclic Carbene Ligands

Ke Gao, Shinya Otsuka, Alexandre Baralle, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka

J. Synth. Org. Chem. Jpn. 2016 74 1119–1127.

DOI: 10.5059/yukigoseikyokaishi.74.1119


Aromatic Metamorphosis of Dibenzothiophenes

Hideki Yorimitsu*, Dhananjayan Vasu, M. Bhanuchandra, Kei Murakami, and Atsuhiro Osuka

Synlett 2016, 27, 1765–1774.

DOI: 10.1055/s-0035-1561617