Creation of novel inorganic-organic hybrid materials using atom, electron, ion, and spin degrees of freedom

Publications

2022.11.24480. Negatively Charged Iron-Bridged Fullerene Dimer {Fe(CO)2‑μ2‑η22‑C60}22−
M. A. Faraonov, A. V. Kuzmin, S. S. Khasanov, A. F. Shestakov, A. Otsuka, H. Yamochi, H. Kitagawa, D. V. Konarev
Inorganic Chemistry, in press.
2022.10.28479. New HATNA(CN)6 Ligand in the Design of Dianion Magnetic Assemblies with Lanthanides {Cryptand(K+)}2{HATNA(CN)6.3LnIII(TMHD)3}2− (Ln = Gd, Tb and Dy)
M. V. Mikhailenko, V. V. Ivanov, A. V. Kuzmin, M. A. Faraonov, A. F. Shestakov, S. S. Khasanov, A. Otsuka, H. Yamochi, H. Kitagawa, D. V. Konarev
Polyhedron, in press.
2022.10.28478. Observation of an Alternate Charge-Polarization State in a One-Dimensional Pt–Pt–I Chain Compound with a Bulky Pendant Ligand
H. Moriyama, K. Otsubo, K. Sugimoto, S. Kawaguchi,  H. Kitagawa
Angew. Chem. Int. Ed., in press.
2022.10.25477. Crystalline Paramagnetic Supramolecular 2D-Polymer of the Tetra(4-pyridyl)porphyrin and Terbium(III) Complex
D. I Nazarov, M. A. Faraonov, A. V. Kuzmin, S. S. Khasanov, A. Otsuka, H. Yamochi, H. Kitagawa, D. V. Konarev
Dalton Transactions, 51, 16921-16925 (2022).
2022.10.22476. High-Performance All-Solid-State Proton Rectifier Using a Heterogeneous Membrane Composed of Coordination Polymer and Layered Double Hydroxide
J. Lu, Y. Yoshida, M. Maesato, H. Kitagawa
Angew. Chem. Int. Ed., e202213077.
2022.09.12475. Chemical Synthesis, Characterization and Properties of Multi-Element Nanoparticles
K. Kusada, M. Mukoyoshi, D. Wu, H. Kitagawa
Angew. Chem. Int. Ed., 61, e202209616 (2022) (Invited Review).
2022.09.03474. Nanoparticle/Metal-organic Framework Hybrid Catalysts: Elucidating the Role of the MOF
M. Mukoyoshi and H. Kitagawa
Chemical Communications, 58, 10757-10767 (2022) (Invited Review).
2022.08.26473. Rational Construction of Molecular Electron-conducting Nanowires Encapsulated in Proton-conducting Matrix in a Charge Transfer Salt
M. Donoshita, Y. Yoshida, M. Maesato, H. Kitagawa
J. Am. Chem. Soc., 144, 17149-17155 (2022).
2022.08.16472. Synthesis, Characterization, Computational and Biological Activity of Some Schiff Bases and Their Fe, Cu and Zn Complexes
T. M. A. Al-Shboul, M. El-khateeb, Z. H. Obeidat, T. S. Ababneh, S. S. Al-Tarawneh, M. S. A. Zoubi, W. Alshaer, A. A. Seni, T. Qasem, H. Moriyama, Y. Yoshida, H. Kitagawa, T. M. A. Jazzazi
Inorganic, 10, 112 (2022).
2022.06.23471. Continuous-Flow Reactor Synthesis for Homogeneous 1-nm-Sized Extremely Small High-Entropy Alloy Nanoparticles
H. Minamihara, K. Kusada, D. Wu, T. Yamamoto, T. Toriyama, S. Matsumura, L. Kumara, K. Ohara, O. Sakata, S. Kawaguchi, Y. Kubota, H. Kitagawa
J. Am. Chem. Soc., 144, 11525-11529 (2022).
2022.06.11470. Trinuclear Coordination Assemblies of Low-spin Dicyano Manganese(II) (S = 1/2) and Iron(II) (S = 0) Phthalocyanines with Manganese(II) Acetylacetonate and Tris(cyclopentadienyl)gadolinium(III) and Neodymium(III)
N. R. Romanenko, A. V. Kuzmin, M. V. Mikhailenko, M. A. Faraonov, S. S. Khasanov, E. I. Yudanova, A. F. Shestakov, A. Otsuka, H. Yamochi, H. Kitagawa, D. V. Konareva
Dalton Transactions, 51, 9770-9779 (2022).
2022.06.10469. Effects of Thiolate Size on Their Coordination to Palladium Phosphine Fragments
M. El-khateeb, H. Moriyama, Y. Yoshida, H. Kitagawa
Polyhedron, 223, 115949 (2022).
2022.05.21468. The Effect of Ru Precursor and Support on the Hydrogenation of Aromatic Aldehydes/Ketones to Alcohols
C. Chaudhari, K. Sato, S. Miyahara, T. Yamamoto, T. Toriyama, S. Matsumura, K. Kusada, H. Kitagawa, K. Nagaoka
ChemCatChem, in press.
2022.05.07467. Compositional Dependence of Structures and Hydrogen Evolution Reaction Activity of Platinum-Group-Metal Quinary RuRhPdIrPt Alloy Nanoparticles
Y. Maruta, K. Kusada, D. Wu, T. Yamamoto, T. Toriyama, S. Matsumura, O. Seo, S. Yasuno, O. Sakata, S. Kawaguchi, Y. Kubota, H. Kitagawa
Chemical Communications, 58, 6421-6424 (2022).
2022.04.29466. Systematic Tuning of Magnetic Properties in Mixed-Metal MOF-74
M. Mukoyoshi, M. Maesato, S. Kawaguchi, Y. Kubota, K. Cho, Y. Kitagawa, H. Kitagawa
Inorganic Chemistry, 61, 7226-7230 (2022).
2022.04.26465. Strong Proton–Electron Coupling in π-Planar Metal Complex with Redox-Active Ligands
P. Huang, Y. Yoshida, M. Hayashi, Y. Nakano, H. Yamochi, H. Kitagawa
Angew. Chem. Int. Ed., 61, e202204521 (2022).
2022.03.22464. Slow Synthesis Methodology-Directed Immiscible Octahedral PdxRh1-x Dual-Atom-Site Catalysts for Superior Three-Way Catalytic Activities over Rh
Z. Tan, M. Haneda, H. Kitagawa, B. Huang
Angew. Chem. Int. Ed., 61, e202202588 (2022).
2022.02.26463. High-Temperature Quantum Tunneling and Hydrogen Bonding Rearrangements Characterize the Solid-Solid Phase Transitions in a Phosphonium-Based Protic Ionic Liquid
A. E. Khudozhitkov, M. Donoshita, A. G. Stepanov, F. Philippi, D. Rauber, R. Hempelmann, H. Kitagawa, D. I. Kolokolov, R. Ludwig
Chemistry - A European Journal, 28, e202200257 (2022).
2022.02.19462. An Approach to an Ideal Molecule-Based Mixed Conductor with Comparable Proton and Electron Conductivity
Y. Kimura, Y. Yoshida, Y. Tanaka, M. Maesato, T. Komatsu, H. Kitagawa
Inorganic Chemistry, 61, 4453-4458 (2022).
2022.02.15461. Enhancing Hydrogen Storage Capacity of Pd Nanoparticles by Sandwiching between Inorganic Nanosheets
K. Ament, H. Kobayashi, K. Kusada, J. Breu, H. Kitagawa
Z. Anorg. Allg. Chem., 648, e202100370 (2022).
2022.02.13460. Self-Assembly Ultrathin Fe-BDC as Synergistic Catalytic Platforms for Selective Hydrogenation
Q. Liu, J. Xian, Y. Li, Q. Zhang, H. Kitagawa, G. Li
CCS Chemistry, in press.
2022.02.12459. Crystal Structure Control of Binary and Ternary Solid-Solution Al-loy Nanoparticles with a Face-Centered Cubic or Hexagonal Close-Packed Phase
Q. Zhang, K. Kusada, D. Wu, T. Yamamoto, T. Toriyama, S. Matsumura, S. Kawaguchi, Y. Kubota, H. Kitagawa
J. Am. Chem. Soc., 144, 4224-4232 (2022).
2022.02.11458. Hydrogen Absorption and Diffusion Behaviors in Cube-Shaped Palladium Nanoparticles Revealed by Ambient-Pressure X-ray Photoelectron Spectroscopy
J. Tang, O. Seo, D. S. R. Rocabado, T. Koitaya, S. Yamamoto, Y. Nanba, C. Song, J. Kim, A. Yoshigoe, M. Koyama, S. Dekura, H. Kobayashi, H. Kitagawa, O. Sakata, I. Matsuda, J. Yoshinobu
Applied Surface Science, 587, 152797 (2022).
2022.02.04457. Noble-Metal High-Entropy-Alloy Nanoparticles: Atomic-Level In-sight into the Electronic Structure
D. Wu, K. Kusada, Y. Nanba, M. Koyama, T. Yamamoto, T. Toriyama, S. Matsumura, O. SEO, I. Gueye, J. Kim, L. Kumara, R. Singgapulige, O. Sakata, S. Kawaguchi, Y. Kubota, H. Kitagawa
J. Am. Chem. Soc., 144, 3365-3369 (2022).
2022.02.01456. Reversible One- to Two- to Three-Dimensional Transformation in CuII Coordination Polymer
Y. Jing, Y. Yoshida, P. Huang, H. Kitagawa
Angew. Chem. Int. Ed., 61, e202117417 (2022).
2022.01.23455. Mono- and Di-thiocarbonato Complexes of Ruthenium CpRu(CO)2SC(E)E′R (E, E′= O, S)
M. El-khateeb, D. Alsabah, A. K. Hijazi, H. Moriyama, Y. Yoshida, H. Kitagawa
Inorganica Chimica Acta, 534, 120824 (2022).
2022.01.13454. Complexes of Transition Metal Carbonyl Clusters with Tin(II) Phthalocyanine in Neutral and Radical Anion States: Methods of Synthesis, Structures and Properties
N.R. Romanenko, A.V. Kuzmin, S.S. Khasanov, E. I. Yudanova, Y. Nakano, A. Otsuka, H. Yamochi, H. Kitagawa, D.V. Konarev
Dalton Transactions, 51, 2226-2237 (2022).
2021.12.01453. A Preinstalled Protic Cation as a Switch for Superprotonic Conduction in a Metal-Organic Framework
K. Otsubo, S. Nagayama, S. Kawaguchi, K. Sugimoto,H. Kitagawa
JACS Au, 2, 109-115 (2022).
2021.11.17452. Continuous-Flow Syntheses of Alloy Nanoparticles
K. Kusada and H. Kitagawa
Materials Horizons, 9, 547-558 (2022) (Invited Review).
2021.10.20451. Phase Control of Solid-solution Nanoparticles Beyond the Phase Diagram for Enhanced Catalytic Property
D. Wu, K. Kusada, S. Aspera, H. Nakanishi, Y. Chen, O. Seo, C. Song, J. Kim, S. Hiroi, O. Sakata, T. Yamamoto, S. Matsumura, Y. Nanba, M. Koyama, N. Ogiwara, S. Kawaguchi, Y. Kubota, H. Kitagawa
ACS Materials Au, 2, 110-116 (2022).
2021.12.25450. Quantitative Characterization of the Thermally-Driven Alloying State in Ternary Ir-Pd-Ru Nanoparticles
X. Q. Tran, K. Aso, T. Yamamoto, W. Yang, Y. Kono, K. Kusada, D. Wu, H. Kitagawa, S. Matsumura
ACS Nano, 16, 1612-1624 (2022).
2021.11.11449. Synthesis of Hexaazatriphenylene Charge-Transfer Complexes and Their Application in Cathode Active Materials for Lithium-Ion Batteries
K. Nakao, Y. Kamakura, M. Fujiwara, T. Shimizu, Y. Yoshida, H. Kitagawa, H. Yoshikawa, Y. Kitagawa, D. Tanaka
Crystal Growth & Design, 22, 26-31 (2022).
2021.11.08448. C-supported WOx-Ru based Catalysts for the Selective Hydrogenolysis of Glycerol to 1,2-Propanediol
A. Belle, K. Kusada, H. Kitagawa, A. Perosa, L. Castoldi, D. Polidoro, M. Selva
Catalysis Science & Technology, 12, 259-272 (2022).
2022.01.09447. Weak Antiferromagnetic Exchange and Ferromagnetic Alignment of FeII (S = 2) Spins in Differently Charged {HAT×(FeIICl2)3}n (n = 2- and 3-) Assemblies of Hexaazatriphenylenes (HAT)
D. Konarev, M. V. Mikhailenko, S. S. Khasanov, A. F. Shestakov, A. V. K. Kuzmin, A. Otsuka, H. Yamochi, H. Kitagawa
Chemistry - A European Journal, 28, e202104165 (2022).
2021.08.20446. Strain-Controlled Spin Transition in Heterostructured Metal-Organic Framework Thin Film
T. Haraguchi, K. Otsubo, O. Sakata, A. Fujiwara, H. Kitagawa
J. Am. Chem. Soc., 143, 16128-16135 (2021).
2021.08.20445. Fabrication of Integrated Copper-Based Nanoparticles/Amorphous Metal-Organic Framework by Facile Spray-Drying Method: Highly Enhanced CO2 Hydrogenation Activity for Methanol Synthesis
Y. Mitsuka, H. Kobayashi, N. Ogiwara, T. Yamamoto, T. Toriyama, S. Matsumura, M. Haneda, S. Kawaguchi, Y. Kubota, H. Kitagawa
Angew. Chem. Int. Ed., 60, 22283-22288 (2021).
2021.08.20444. Various Stacking Patterns of Two-Dimensional Molecular Assemblies in Hydrogen-Bonded Cocrystals: Insight on Competitive Intermolecular Interactions and Control of Stacking Patterns
M. Donoshita, Y. Yoshida, M. Hayashi, R. Ikeda, S. Tanaka, Y. Yamamura, K. Saito, S. Kawaguchi, K. Sugimoto, H. Kitagawa
Angew. Chem. Int. Ed., 60, 22839-22848 (2021).

News / Articles / Award

2022.08.24
Yuki Tanaka(M2)
Physical properties of quantum spin liquid candidate κ-(ET)2Cu[Au(CN)2]Cl at low temperatures and high pressures
The 29th International Conference on LOW TEMPERATURE PHYSICS "The Best Poster Award"
2022.05.23
NHK NEWS WEB
2022.05.22
Hiroki Minamihara (M2)
Continuous-Flow Reactor Synthesis for 1-nm-Sized Platinum Group High-Entropy Alloy Nanoparticles and Evaluation of Their Hydrogen Evolution Catalytic Activity
The 20th Annual Meeting of the Society of Nano Science and Technology "Young Best Presentation Award"
2022.05.17
日刊工業新聞
2022.04.28
(京大院理)青木 健太郎 (D3)
Structure and Magnetic Properties of a Dimerized Trinuclear Ni String Complex
日本化学会第102回春季年会「学生講演賞」
2022.04.20
Business Insider Japan
2022.04.13
(京大白眉セ)草田 康平(特定准教授)
『機能性非平衡固溶ナノ合金の開発と相制御に関する研究』
令和4年度 文部科学大臣表彰 若手科学者賞
2022.04.06
京都新聞
2022.04.05
日刊工業新聞
2022.03.30
毎日新聞
2022.03.25
JST「サイエンスポータル」
2022.03.16
化学工業日報
2022.03.16
京都新聞
2022.03.14
朝日新聞
2022.03.02
日経産業新聞
2022.02.24
化学工業日報
2022.02.16
朝日新聞
2022.01.26
(京大院理)北川 宏(教授)他
非平衡合成による多元素ナノ合金の原子分解能構造解析
文部科学省ナノテクノロジープラットフォーム 令和3年度「秀でた利用成果」優秀賞
2021.12.22
(京大白眉セ)草田 康平(特定准教授)
『非平衡合成法を用いた固溶化と相制御による機能性金属ナノ粒子の開発』
日本化学会第71回進歩賞
2021.9.16
(京大院理)青木 健太郎 (D3)
Synthesis, Structure and Magnetic Property of Dimerized Trinuclear Complex, Ni6Cl2(dpa)8(I5)2 (dpa = dipyridylamido anion)
第71回錯体化学討論会 「ポスター賞」(CrystEngComm賞)

Creation of novel inorganic-organic hybrid materials using atom, electron, ion, and spin degrees of freedom

We believe that the establishment of an innovative science and technology “protoelectronics”
based on the fusion of electrons and hydrogen (protons) will be a breakthrough in near future.
In our laboratory, we aim at the flexible construction and control of quantum electronic
(superconducting, ferromagnetic, ferroelectric, metallic, insulating, etc.) and ionic phases
(especially superionic conduction, tunneling, and quantum paraelectric phases based on protons).

Research Outline

NEWS TOPICS